Electrochemical Analysis

1663 words - 7 pages

Electrochemical Analysis
Introduction:
In 1791 Luigi Galvanic discovered electrical activity in the nerves of the frogs that he was dissecting. He thought that electricity was of animal origin and could be found only in living tissues. A few years later, in 1800 Alessandro Volta discovered that electricity could be produced through inorganic means. In fact, by using small sheets of copper and zinc and cloth spacers soaked in an acid solution, he built a battery - the first apparatus capable of producing electricity. Naysayers were quick to predict that electricity would never serve a useful purpose. Obviously they were very wrong. Electricity has a central role in our lives and to this ...view middle of the document...

A barrier of just one sheet would be too permeable, therefore use at least three layers of paper when building this device.
Controlling and Measuring Current and Potential:
Electrochemical measurements are made in an electrochemical cell, consisting of two or more electrodes and associated electronics for controlling and measuring the current and potential. In this section the basic components of electrochemical instrumentation are introduced. Specific experimental designs are considered in greater detail in the sections that follow.
The simplest electrochemical cell uses two electrodes. The potential of one of the electrodes is sensitive to the analyte’s concentration and is called the working, or indicator electrode. The second electrode, which is called the counter electrode, serves to complete the electric circuit and provides a reference potential against which the working electrode’s potential is measured. Ideally the counter electrode’s potential remains constant so that any change in the overall cell potential is attributed to the working electrode. In a dynamic method, where the passage of current changes the concentration of species in the electrochemical cell, the potential of the counter electrode may change over time. This problem is eliminated by replacing the counter electrode with two electrodes: a reference electrode, through which no current flows and whose potential remains constant; and an auxiliary electrode that completes the electric circuit and through which current is allowed to flow.
Although many different electrochemical methods of analysis are possible there are only three basic experimental designs: (1) measuring the potential under static conditions of no current flow; (2) measuring the potential while controlling the current; and (3) measuring the current while controlling the potential. Each of these experimental designs, however, is based on Ohm’s law that a current, i, passing through an electric circuit of resistance, R, generates a potential, E; thus
E = iR
Each of these experimental designs also uses a different type of instrument. To aid in understanding how they control and measure current and potential, these instruments are described as if they were operated manually. To do so the analyst observes a change in current or potential and manually adjusts the instrument’s settings to maintain the desired experimental conditions. It is important to understand that modern electrochemical instruments provide an automated, electronic means of controlling and measuring current and potential. They do so by using very different electronic circuitry than that shown here.
Auxiliary electrode: The third electrode in a three-electrode cell that completes the circuit.
Ohm’s law: The statement that the current moving through a circuit is proportional to the applied potential and inversely proportional to the circuit’s resistance (E = iR).
Potentiometer: A device for measuring the potential of an...

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