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Periodic Table Essay

2732 words - 11 pages

First systemization attempts
In 1789, Antoine Lavoisier published a list of 33 chemical elements, grouping them into gases, metals, nonmetals, and earths; Chemists spent the following century searching for a more precise classification scheme. In 1829, Johann Wolfgang Döbereiner observed that many of the elements could be grouped into triads based on their chemical properties.Lithium, sodium, and potassium, for example, were grouped together in a triad as soft, reactive metals. Döbereiner also observed that, when arranged by atomic weight, the second member of each triad was roughly the average of the first and the third; this ...view middle of the document...

[7] Newlands was nonetheless able to draft a table of the elements and used it to predict the existence of missing elements, such as germanium. The Chemical Society only acknowledged the significance of his discoveries five years after they credited Mendeleev.[8]
Mendeleev's table
Dmitri Mendeleev

Mendeleev's 1869 periodic table; note that his arrangement presents the periods vertically, and the groups horizontally.
Russian chemistry professor Dmitri Mendeleev and German chemist Julius Lothar Meyerindependently published their periodic tables in 1869 and 1870, respectively. They both constructed their tables by listing the elements in rows or columns in order of atomic weight and starting a new row or column when the characteristics of the elements began to repeat. The success of Mendeleev's table came from two decisions he made. The first was to leave gaps in the table when it seemed that the corresponding element had not yet been discovered. Mendeleev was not the first chemist to do so, but he was the first to be recognized as using the trends in his periodic table to predict the properties of those missing elements, such as gallium and germanium. The second decision was to occasionally ignore the order suggested by the atomic weights and switch adjacent elements, such as cobalt and nickel, to better classify them into chemical families. With the development of theories of atomic structure, it became apparent that Mendeleev had listed the elements in order of increasing atomic number or nuclear charge.
Further development
In the years following publication of Mendeleev's periodic table, the gaps he identified were filled as chemists discovered additional naturally occurring elements. It is often stated that the last naturally occurring element to be discovered was francium (referred to by Mendeleev as eka-caesium) in 1939.However, plutonium, produced synthetically in 1940, was identified in trace quantities as a naturally occurring primordial element in 1971, and in 2011 it was found that all the elements up to californium can occur naturally in trace amounts in uranium ores by neutron capture and beta decay.
With the development of modern quantum mechanical theories of electron configurations within atoms, it became apparent that each period (row) in the table corresponded to the filling of a quantum shell of electrons. Larger atoms have more electron sub-shells, so modern tables have progressively longer periods further down the table.
Although minute quantities of some transuranic elements occur naturally,[17] they were all first discovered in laboratories. Their production has expanded the periodic table significantly, the first of these being neptunium, synthesized in 1939.Because many of the transuranic elements are highly unstable and decay quickly, they are challenging to detect and characterize when produced. There have been controversies concerning the acceptance of competing discovery claims for some elements,...

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